Adelaide Research & Scholarship
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https://hdl.handle.net/2440/105989
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| Type: | Journal article |
| Title: | Biomimetic total synthesis of rhodonoids C and D, and murrayakonine D |
| Author: | Day, A. Lamr, H. Sumby, C. George, J. |
| Citation: | Organic Letters, 2017; 19(10):2463-2465 |
| Publisher: | American Chemical Society |
| Issue Date: | 2017 |
| ISSN: | 1523-7060 1523-7052 |
| Statement of Responsibility: | Aaron J. Day, Hiu C. Lam, Christopher J. Sumby and Jonathan H. George |
| Abstract: | A divergent, three-step total synthesis of rhodonoids C and D has been achieved using a biosynthetically inspired, acid-catalyzed cascade cyclization of an epoxy-chromene that involves the presumed intermediacy of o-quinone methides. Application of a similar strategy also allowed synthesis of the alkaloid murrayakonine D. |
| Keywords: | Terpenes Benzopyrans Biomimetics Molecular Structure Cyclization Stereoisomerism |
| Rights: | © 2017 American Chemical Society |
| DOI: | 10.1021/acs.orglett.7b00779 |
| Grant ID: | http://purl.org/au-research/grants/arc/DP160103393 |
| Published version: | http://dx.doi.org/10.1021/acs.orglett.7b00779 |
| Appears in Collections: | Aurora harvest 3 Chemistry publications |
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