Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/129433
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dc.contributor.author | Gemoets, H.P.L. | - |
dc.contributor.author | Hessel, V. | - |
dc.contributor.author | Noël, T. | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | Organic Letters, 2014; 16(21):5800-5803 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.issn | 1523-7052 | - |
dc.identifier.uri | http://hdl.handle.net/2440/129433 | - |
dc.description.abstract | Herein, we report the first site-selective, Pd(II)-catalyzed, cross-dehydrogenative Heck reaction of indoles in micro flow. By use of a capillary microreactor, we were able to boost the intrinsic kinetics to accelerate former hour-scale reaction conditions in batch to the minute range in flow. The synergistic use of microreactor technology and oxygen, as both terminal oxidant and mixing motif, highlights the sustainable aspect of this process. | - |
dc.description.statementofresponsibility | Hannes P. L. Gemoets, Volker Hessel, and Timothy Noël | - |
dc.language.iso | en | - |
dc.publisher | American Chemical Society | - |
dc.rights | © 2014 American Chemical Society | - |
dc.source.uri | http://dx.doi.org/10.1021/ol502910e | - |
dc.subject | Oxygen | - |
dc.subject | Palladium | - |
dc.subject | Alkenes | - |
dc.subject | Indoles | - |
dc.subject | Oxidants | - |
dc.subject | Molecular Structure | - |
dc.subject | Kinetics | - |
dc.subject | Catalysis | - |
dc.subject | Hydrogen Bonding | - |
dc.title | Aerobic C-H olefination of indoles via a cross-dehydrogenative coupling in continuous flow | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/ol502910e | - |
dc.relation.grant | ECHO 713.013.001 | - |
dc.relation.grant | VENI 12464 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Hessel, V. [0000-0002-9494-1519] | - |
Appears in Collections: | Aurora harvest 4 Chemistry publications |
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