Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/130359
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Type: | Journal article |
Title: | Electrochemical activity of nitrogen-containing groups in organic molecule electrode materials and their improvement strategies |
Author: | Yu, Q. Xue, Z. Wang, S. Yu, J. Na, J. Yamauchi, Y. |
Citation: | Advanced Energy Materials, 2021; 11(7):2002523-1-2002523-25 |
Publisher: | Wiley |
Issue Date: | 2021 |
ISSN: | 1614-6832 1614-6840 |
Statement of Responsibility: | Qianchuan Yu, Zhihuan Xue, Meichen Li, Peimeng Qiu, Changgang Li, Shengping Wang, Jingxian Yu, Hiroki Nara, Jongbeom Na, and Yusuke Yamauchi |
Abstract: | In recent years, due to their structural diversity, adjustability, versatility, and excellent electrochemical properties, organic compounds with nitrogen-containing groups (OCNs) have become some of the most promising organic electrode materials. The nitrogen-containing groups acting as electrochemical active sites include carbon–nitrogen groups, nitrogen–nitrogen groups, nitrogen–oxygen groups in OCNs, and nitrogen-containing groups in covalent organic frameworks. The molecular structure regulation of OCNs with nitrogen-containing groups acting as electrochemical active centers can suppress dissolution in electrolytes, increase electronic conductivity, and improve the kinetics of redox reactions. The kinetics behavior and electrochemical characteristics of OCN electrode materials in alkali metal rechargeable batteries with organic electrolytes are reviewed, and the related relationships between the structure and electrochemical properties of OCNs are the core of this review. Herein, the electrochemical reaction mechanisms and the strategies to improve the electrochemical activity of nitrogen-containing groups in OCNs are clarified, and the conjugate molecular structure of OCNs is shown to be an important direction for improvement. These results will have implications for research on electrode materials and provide more choices for rechargeable batteries. Moreover, this work will guide the study of more efficient OCNs that can be used as electrode materials. |
Keywords: | covalent organic frameworks; electrochemical activity; electrode materials; nitrogen-containing groups |
Description: | Published online: January 12, 2021 |
Rights: | © 2021 Wiley-VCH GmbH |
DOI: | 10.1002/aenm.202002523 |
Grant ID: | http://purl.org/au-research/grants/arc/CE140100003 http://purl.org/au-research/grants/arc/DP180101581 http://purl.org/au-research/grants/arc/LP180100429 |
Published version: | http://dx.doi.org/10.1002/aenm.202002523 |
Appears in Collections: | Aurora harvest 4 Chemistry publications |
Files in This Item:
File | Description | Size | Format | |
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hdl_130359_Coversheet.pdf | Coversheet | 427.02 kB | Adobe PDF | View/Open |
hdl_130359.pdf | Accepted version | 5.72 MB | Adobe PDF | View/Open |
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