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https://hdl.handle.net/2440/133717
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Type: | Journal article |
Title: | Facile synthesis of nickel-foam-based nano-architectural composites as binder-free anodes for high capacity Li-ion batteries |
Author: | Min, S. Zhao, C. Ju, P. Zhou, T. Gao, H. Zheng, Y. Wang, H. Chen, G. Qian, X. Guo, Z. |
Citation: | Journal of Power Sources, 2016; 304:311-318 |
Publisher: | Elsevier |
Issue Date: | 2016 |
ISSN: | 0378-7753 1873-2755 |
Statement of Responsibility: | Shudi Min, Chongju Zhao, Peiwen Ju, Tengfei Zhou, Hong Gao, Yang Zheng ... et al. |
Abstract: | A series of nickel foam (NF)-based composites of MxOy/RGO/Ni(OH)2 [MxOy = Co3O4, MnO2, and Ni(OH)2] with diverse multilayer nano-architectures were designed and grown in situ on NF through a one-pot hydrothermal process. Based on the redox reaction between the active NF substrate and graphene oxide (GO), along with electrostatic forces between the Mn+ ions and GO in the solution, strong interactions take place at the interfaces of MxOy/RGO, RGO/Ni(OH)2, and Ni(OH)2/Ni, and thus, there is good contact for electron transfer. These MxOy/RGO/Ni(OH)2 samples were directly used as conductive-agent- and binder-free anodes for lithium ion batteries (LIBs), and the Ni(OH)2/RGO/Ni(OH)2/NF composite electrode showed a high specific capacity, good rate capability, and excellent cycling stability, especially, it had a high reversible capacity of about 1330 mAh g−1 even after 200 cycles at 100 mA g−1. This general strategy presents a promising route for the design and synthesis of various multilayer nano-architectural transition metal oxides (hydroxide)/RGO composites on NF as energy storage materials. |
Rights: | © 2015 Elsevier B.V. All rights reserved. |
DOI: | 10.1016/j.jpowsour.2015.11.053 |
Grant ID: | http://purl.org/au-research/grants/arc/DP1094261 |
Published version: | http://dx.doi.org/10.1016/j.jpowsour.2015.11.053 |
Appears in Collections: | Electrical and Electronic Engineering publications |
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