Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/17805
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | 1,2-dioxines containing tethered hydroxyl functionality as convenient precursors for pyran syntheses |
Author: | Avery, T. Caiazza, D. Culbert, J. Taylor, D. Tiekink, E. |
Citation: | Journal of Organic Chemistry, 2005; 70(21):8344-8351 |
Publisher: | Amer Chemical Soc |
Issue Date: | 2005 |
ISSN: | 0022-3263 1520-6904 |
Statement of Responsibility: | Thomas D. Avery, Daniela Caiazza, Julie A. Culbert, Dennis K. Taylor, and Edward R. T. Tiekink |
Abstract: | A new method for the construction of tetrahydropyrans derived from readily available 1,2-dioxines containing a tethered hydroxyl moiety is described. The reaction proceeds via a base-catalyzed rearrangement of the 1,2-dioxines to either the isomeric cis or trans -hydroxy enones followed by intramolecular oxa-Michael addition of the tethered hydroxyl group. |
Keywords: | Hydroxyl Radical Heterocyclic Compounds, 1-Ring Pyrans Anticholesteremic Agents Molecular Structure Antimitotic Agents |
Description: | Copyright © 2005 American Chemical Society |
DOI: | 10.1021/jo050806n |
Published version: | http://dx.doi.org/10.1021/jo050806n |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.