Adelaide Research & Scholarship
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https://hdl.handle.net/2440/17984
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| Type: | Journal article |
| Title: | Two gold-ruthenium clusters derived from Ru3(m-H)3(m3-CBr)(CO)9 |
| Author: | Bruce, M. Humphrey, P. Skelton, B. White, A. |
| Citation: | Journal of Organometallic Chemistry, 2004; 689(15):2558-2561 |
| Publisher: | Elsevier Science Sa |
| Issue Date: | 2004 |
| ISSN: | 0022-328X |
| Statement of Responsibility: | Michael I. Bruce, Paul A. Humphrey, Brian W. Skelton and Allan H. White |
| Abstract: | The reaction between AuMe(PPh3) and Ru3(μ-H)3(μ3-CBr)(CO)9 (1) affords the novel heptanuclear cluster Au4Ru3 (μ3-CMe)(Br)(CO)9(PPh3)3 (2), containing an Au/Ru3/Au trigonal pyramidal cluster face-capped by two Au(PPh3) groups and a CMe ligand, together with Au2Ru3(μ-H)(μ3-CMe)(CO) 9(PPh3)2 (3), formed by isolobal replacement of two of the three μ-H atoms in 1 by Au(PPh3) groups. The latter co-crystallises with the analogous μ3 -CH complex, as also shown spectroscopically. © 2004 Elsevier B.V. All rights reserved. |
| DOI: | 10.1016/j.jorganchem.2004.04.043 |
| Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
| Published version: | http://dx.doi.org/10.1016/j.jorganchem.2004.04.043 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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