Adelaide Research & Scholarship
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https://hdl.handle.net/2440/18012
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| Type: | Journal article |
| Title: | A domino ring-opening/epoxidation of 1,2-dioxines |
| Author: | Greatrex, B. Taylor, D. Tiekink, E. |
| Citation: | Journal of Organic Chemistry, 2004; 69(7):2580-2583 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2004 |
| ISSN: | 0022-3263 1520-6904 |
| Abstract: | When allowed to react with alkaline hydrogen peroxide, monocyclic 1,2-dioxines ring-open to their isomeric -hydroxyenone intermediates which are rapidly epoxidized to afford trans-4-hydroxy-2,3-epoxyketones in 21-81% yield. In the case of meso-1,2-dioxines, Co(II) complex catalyzed asymmetric ring-opening of the 1,2-dioxine may be employed to furnish enantioenriched epoxides |
| Description: | Copyright © 2004 American Chemical Society |
| DOI: | 10.1021/jo0303315 |
| Published version: | http://dx.doi.org/10.1021/jo0303315 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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