Adelaide Research & Scholarship
Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/23518
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| Type: | Journal article |
| Title: | The first total synthesis of natural grenadamide |
| Author: | Avery, T. Culbert, J. Taylor, D. |
| Citation: | Organic and Biomolecular Chemistry, 2006; 4(2):323-330 |
| Publisher: | Royal Soc Chemistry |
| Issue Date: | 2006 |
| ISSN: | 1477-0520 1477-0539 |
| Abstract: | A concise, high yielding route to the naturally occurring enantiomer of grenadamide utilizing a 3,6-disubstituted 1,2-dioxine starting material is presented. The route allows for ease in synthesizing grenadamide derivatives varying at cyclopropyl carbons 2 and 3, with access to both enantiomers. Evidence for phosphorus-assisted deprotonation of 1,2-dioxines is also discussed. |
| Keywords: | Phosphorus Amides Cyclopropanes Stereoisomerism |
| Description: | © The Royal Society of Chemistry 2006 The document attached has been archived with permission from the publisher. |
| DOI: | 10.1039/b513774h |
| Published version: | http://pubs.rsc.org/en/Content/ArticleLanding/2006/OB/b513774h |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
Files in This Item:
| File | Description | Size | Format | |
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| hdl_23518.pdf | 202.82 kB | Publisher's PDF | View/Open |
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