Adelaide Research & Scholarship
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https://hdl.handle.net/2440/34490
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| Type: | Journal article |
| Title: | Disentangling disorder in the three-dimensional coordination network of {Ag₃[Tris(2-pyridylmethyl)cyclotriguaiacylene]₂}(PF₆)₃ |
| Other Titles: | Disentangling disorder in the three-dimensional coordination network of {Ag(3)[Tris(2-pyridylmethyl)cyclotriguaiacylene](2)}(PF(6))(3) |
| Author: | Sumby, C. Hardie, M. |
| Citation: | Crystal Growth and Design, 2005; 5(4):1321-1324 |
| Publisher: | American Chemical Society |
| Issue Date: | 2005 |
| ISSN: | 1528-7483 1528-7505 |
| Statement of Responsibility: | Christopher J. Sumby and Michaele J. Hardie |
| Abstract: | The crystalline complex {Ag3[Tris(2-pyridylmethyl)cyclotriguaiacylene]2}(PF6)3 has been synthesized and shown by X-ray crystallography to have a disordered three-dimensional cubic coordination network structure. The coordination network features a back-to-back stacking of the molecular host-type ligands into tetrahedral clusters, and the PF6- anions act as both intracavity guests and lattice-type guests. Disentangling the network disorder gives a 4-fold interpenetrating (10,3)-a net. |
| Description: | Copyright © 2005 American Chemical Society |
| DOI: | 10.1021/cg050061e |
| Published version: | http://dx.doi.org/10.1021/cg050061e |
| Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
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