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https://hdl.handle.net/2440/34875
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Type: | Journal article |
Title: | Interwoven 2-D coordination network prepared from the molecular host Tris(isonicotinoyl)cyclotriguaiacylene and Silver(I) Cobalt(III) bis(dicarbollide) |
Author: | Hardie, M. Sumby, C. |
Citation: | Inorganic Chemistry: including bioinorganic chemistry, 2004; 43(22):6872-6874 |
Publisher: | Amer Chemical Soc |
Issue Date: | 2004 |
ISSN: | 0020-1669 1520-510X |
Statement of Responsibility: | Michaele J. Hardie and Christopher J. Sumby |
Abstract: | A new 3-fold symmetric molecular host, tris(isonicotinoyl)cyclotriguaiacylene, has been synthesized from cyclotriguaiacylene and isonicotinoyl chloride hydrochloride in 70% yield. Its crystal structure shows dimerization of the host molecules into a capsule-like arrangement. When reacted with Ag[Co(C2B9H11)2], the host forms a 1-D [ML2]n coordination polymer, which assembles into a 2-D interwoven network through a similar dimerization of the host moieties around acetonitrile guests. Thus, the network structure represents an elegant example whereby the solid state structure of the building blocks is echoed in the resulting supramolecular assembly. The 2-D sheets are further stabilized by π···π stacking interactions between pyridyl donors of alternate 1-D coordination polymers. |
Description: | Copyright © 2004 American Chemical Society |
DOI: | 10.1021/ic049160s |
Published version: | http://pubs.acs.org/cgi-bin/abstract.cgi/inocaj/2004/43/i22/abs/ic049160s.html |
Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
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