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https://hdl.handle.net/2440/4297
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Type: | Journal article |
Title: | {D-1,4,7,10 -Tetrakis[(S)-2-hydroxy-propyl-kO]-1,4,7,10-tetraazacyclododecane-k4N}cadmium(II) 4-nitro-phenolate hydrate |
Author: | Davies, P. Lincoln, S. Smith, C. Taylor, M. Wainwright, K. Wallwork, K. |
Citation: | Acta Crystallographica Section C: Crystal Structure Communications, 2000; C56(1):28-30 |
Publisher: | Blackwell Munksgaard |
Issue Date: | 2000 |
ISSN: | 0108-2701 1600-5759 |
Statement of Responsibility: | Philip. J. Davies, Stephen F. Lincoln, Christopher B. Smith, Max R. Taylor, Kevin P. Wainwright and Kia S. Wallwork |
Abstract: | Crystallization of [Cd(S-thpc12)](ClO4)2·H2O {S-thpc12 is 1,4,7,10-tetrakis[(S)-2-hydroxypropyl]-1,4,7,10-tetraazacyclododecane} in the presence of sodium p-nitrophenolate forms the title complex, [Cd(C20H44N4O4)](C6H 4NO3)(ClO4)·H2O. in which p-nitrophenolate and water separately hydrogen bond to a different pair of cis-related pendant hydroxyl groups which, together with the four N atoms, are themselves hound to CdII in an approximately square antiprismatic arrangement. The diastereoselectivity of the complex-forming process is apparent from the fact that both different disymmetric cations in the asymmetric unit have the same Δ helicity. |
Description: | Copyright © 2008 International Union of Crystallography |
DOI: | 10.1107/S0108270199012391 |
Published version: | http://dx.doi.org/10.1107/s0108270199012391 |
Appears in Collections: | Aurora harvest 6 Chemistry publications Environment Institute publications |
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