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https://hdl.handle.net/2440/4338
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Type: | Journal article |
Title: | Preparation and molecular structures of FcC ≡ CI and {Co₂(CO)₆}₂(µ:µ-FcC₂C₂Fc) [Fc = Ferrocenyl, (h-C₅H₄)Fe(h-C₅H₅)] |
Other Titles: | Preparation and molecular structures of FcC triple bar CI and {Co(2)(CO)(6)}(2)(mu:mu-FcC(2)C(2)Fc) [Fc = Ferrocenyl, (h-C(5)H(4))Fe(h-C(5)H(5))] |
Author: | Bruce, M. Skelton, B. Smith, M. White, A. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1999; 52(6):431-435 |
Publisher: | CSIRO |
Issue Date: | 1999 |
ISSN: | 0004-9425 |
Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Mark E. Smith and Allan H. White |
Abstract: | Iodination of FcC ≡ CH with morpholinium iodide gave structurally characterized iodoethynylferrocene, FcC ≡ CI; its reaction with Co2(CO)8 affords {Co2(CO)6}2(µ:µ-FcC2C2Fc), also characterized by an X-ray structure determination. This compound is formed by deiodinative coupling of the iodoalkyne and subsequent addition of a Co2(CO)6 group to each C ≡ C triple bond in the resulting diyne |
Rights: | © CSIRO 1999 |
DOI: | 10.1071/CH99024 |
Published version: | http://dx.doi.org/10.1071/ch99024 |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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