Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4338
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Type: Journal article
Title: Preparation and molecular structures of FcC ≡ CI and {Co₂(CO)₆}₂(µ:µ-FcC₂C₂Fc) [Fc = Ferrocenyl, (h-C₅H₄)Fe(h-C₅H₅)]
Other Titles: Preparation and molecular structures of FcC triple bar CI and {Co(2)(CO)(6)}(2)(mu:mu-FcC(2)C(2)Fc) [Fc = Ferrocenyl, (h-C(5)H(4))Fe(h-C(5)H(5))]
Author: Bruce, M.
Skelton, B.
Smith, M.
White, A.
Citation: Australian Journal of Chemistry: an international journal for chemical science, 1999; 52(6):431-435
Publisher: CSIRO
Issue Date: 1999
ISSN: 0004-9425
Statement of
Responsibility: 
Michael I. Bruce, Brian W. Skelton, Mark E. Smith and Allan H. White
Abstract: Iodination of FcC ≡ CH with morpholinium iodide gave structurally characterized iodoethynylferrocene, FcC ≡ CI; its reaction with Co2(CO)8 affords {Co2(CO)6}2(µ:µ-FcC2C2Fc), also characterized by an X-ray structure determination. This compound is formed by deiodinative coupling of the iodoalkyne and subsequent addition of a Co2(CO)6 group to each C ≡ C triple bond in the resulting diyne
Rights: © CSIRO 1999
DOI: 10.1071/CH99024
Published version: http://dx.doi.org/10.1071/ch99024
Appears in Collections:Aurora harvest 6
Chemistry publications

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