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https://hdl.handle.net/2440/4340
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Type: | Journal article |
Title: | Reactions of Ru3(CO)12 with ethyne: molecular structure of Ru2(m-h1,h4:h1,h4-C8H8)(CO)4 |
Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1999; 52(5):413-415 |
Publisher: | CSIRO Publishing |
Issue Date: | 1999 |
ISSN: | 0004-9425 |
Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Natasha N. Zaitseva and Allan H. White |
Abstract: | The reaction between Ru3(CO)12 and ethyne (refluxing tetrahydrofuran, 2 h) produced four binuclear complexes, Ru2(CO)m(C2H2)n [m = 4,n= 4 (1); m = 5,n= 4 (3); m = 7,n= 2 (2), 4 (4)], in low yield. The molecular structure of (1) has been determined by X-ray crystallography and consists of an Ru2(CO)4 group bridged by a C8H8 chain, attached in the µ−η1 ,η4 :η1 ,η4 mode. Structures for the other three complexes are suggested on the basis of their i.r. and mass spectra and similarities with analogous ruthenium complexes obtained from other alkynes. |
Description: | © CSIRO 1999 |
DOI: | 10.1071/CH98151 |
Published version: | http://dx.doi.org/10.1071/ch98151 |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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