Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4342
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| Type: | Journal article |
| Title: | Synthesis and structure of Ru5(m5-C2PPh2)(m-dppm)(m-PPh2)(CO)11.thf |
| Author: | Adams, C. Bruce, M. Skelton, B. White, A. |
| Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1999; 52(5):409-411 |
| Publisher: | CSIRO Publishing |
| Issue Date: | 1999 |
| ISSN: | 0004-9425 |
| Abstract: | <jats:p> The reaction of the open pentanuclear cluster Ru5(µ5-C2PPh2)(µ-PPh2)(CO)13 (1) with dppm afforded the previously described complex Ru5(µ5-C2PPh2)(µ-PPh2)(CO)12(dppm) (2), with six Ru–Ru bonds and a chelating dppm ligand, together with Ru5(µ5-C2PPh2)(µ-dppm)(µ-PPh2)(CO)11 (3), whose structure is reported here (seven Ru–Ru bonds). The bidentate phosphine bridges an outer Ru–Ru vector, adjacent to that bridged by the PPh2 group.</jats:p> |
| DOI: | 10.1071/CH98152 |
| Published version: | http://dx.doi.org/10.1071/ch98152 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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