Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4347
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| Type: | Journal article |
| Title: | ter chemistry. XCIX. An unusual hydrocarbon-cluster bonding mode in Ru3(μ3-2η1,2η3-C14H17Me)(μ-CO)(CO)7, obtained from Ru3(CO)12 and 1,5,9-trimethylcyclododeca-1,5,9-triene |
| Other Titles: | Cluster chemistry. XCIX. An unusual hydrocarbon-cluster bonding mode in Ru3(mu3-2eta1,2eta3-C14H17Me)(mu-CO)(CO)7, obtained from Ru3(CO)12 and 1,5,9-trimethylcyclododeca-1,5,9-triene |
| Author: | Bruce, M. Hinchliffe, J. Skelton, B. White, A. |
| Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1995; 48(9):1651-1657 |
| Publisher: | CSIRO |
| Issue Date: | 1995 |
| ISSN: | 0004-9425 |
| Abstract: | <jats:p>A reaction between Ru3(CO)12 and 1,5,9-trimethylcyclododeca-1,5,9-triene has given the orange-red complex Ru3(μ3-2η1,2η3-C14H17Me)(μ-CO)(CO)7, fully characterized by a single- crystal X-ray study. The hydrocarbon is attached to an irregular closed Ru3 cluster by two Ru -C σ-bonds and two η3-allylic systems, the latter involving exocyclic CH2 and CH groups. The preparation of Ru3(μ-H)(μ3-C12H15)(μ- dppm )(CO)7 is also reported. </jats:p> |
| DOI: | 10.1071/CH9951651 |
| Published version: | http://dx.doi.org/10.1071/ch9951651 |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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