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https://hdl.handle.net/2440/4348
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Type: | Journal article |
Title: | Cyclopentadienyl-ruthenium and osmium chemistry. XL X-ray crystal structures of MBr(PPh₃)₂(η-C₅H₅).CH₂CI₂(M = Ru, Os) |
Other Titles: | Cyclopentadienyl-ruthenium and osmium chemistry. XL X-ray crystal structures of MBr(PPh(3))(2)(eta-C(5)H(5)).CH(2)CI(2)(M = Ru, Os) |
Author: | Tiekink, E. Bruce, M. Low, P. Skelton, B. Werth, A. White, A. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1995; 48(11):1887-1892 |
Publisher: | CSIRO |
Issue Date: | 1995 |
ISSN: | 0004-9425 |
Statement of Responsibility: | MI Bruce, PJ Low, BW Skelton, ERT Tiekink, A Werth and AH White |
Abstract: | <jats:p>The crystal and molecular structures of MBr (PPh3)2(η-C5H5).CH2Cl2 (M = Ru and Os) have been determined. A revised synthesis of the bromo osmium complex is given. The coordination geometry about the metal atom is based on a distorted octahedron with one face being occupied by the cyclopentadienyl group [average Ru -C(Cp) 2.214(3), Os-C(Cp) 2.177(3)Ǻ] and the other by the bromide [ Ru -Br 2.5683(8), Os-Br 2.5438(9)Ǻ] and the two phosphorus atoms [ Ru -P 2.323(2), 2.329(1); Os-P 2.290(2), 2.297(2)Ǻ]. Structural parameters are compared with those of the corresponding chloro complexes and differ only minimally. Crystals of MBr (PPh3)2(η-C5H5).CH2Cl2 are triclinic, space group Pī , with unit cell dimensions ( Ru [Os]): a 14.374(5) [14.276(4)], b 14.057(4) [13.959(3)], c 10.012(5) [9.903(3)]Ǻ, α 99.43(3) [99.79(2)], β 105.60(3) [105.74(2)], γ 100.42(3) [100.39(2)]°, V 1868(1) [1817.7(9)] Ǻ3, Z 2. The structures were refined by a full-matrix least-squares procedure to R 0.050 [0.036] for 7365 [5108] reflections with I ≥ 3σ(I).</jats:p> |
Rights: | © CSIRO 1995 |
DOI: | 10.1071/CH9951887 |
Published version: | http://dx.doi.org/10.1071/ch9951887 |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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