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https://hdl.handle.net/2440/4355
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DC Field | Value | Language |
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dc.contributor.author | Adams, C. | - |
dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Humphrey, P. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 2001 | - |
dc.identifier.citation | Australian Journal of Chemistry: an international journal for chemical science, 2001; 54(5):325-327 | - |
dc.identifier.issn | 0004-9425 | - |
dc.identifier.uri | http://hdl.handle.net/2440/4355 | - |
dc.description.abstract | Addition of K[BHBus3] to {Ru3(µ-PPh2)(CO)9}2(µ3:µ3-C4) (1), followed by acidification, is proposed to give {Ru3H(µ-PPh2)(CO)9}2(µ3:µ3-C=CHCH=C) (2), in which hydrogen atoms have added to each cluster unit and to the C4 fragment of (1) to give a bis(vinylidene) ligand. The osmium analogue has also been prepared. In contrast, the reaction with dihydrogen results in the pentanuclear complex Ru3{µ3:µ-C2C2[Ru2(µ-PPh2)(CO)6]}(µ- PPh2)(CO)9 (3), by cleavage of an Ru(CO)3 fragment from (1). | - |
dc.description.statementofresponsibility | Chris J. Adams, Michael I. Bruce, Paul A. Humphrey, Brian W. Skelton and Allan H. White | - |
dc.language.iso | en | - |
dc.publisher | CSIRO Publishing | - |
dc.rights | © CSIRO 2001 | - |
dc.source.uri | http://www.publish.csiro.au/index.cfm?paper=CH01080 | - |
dc.title | Reactions of {Ru₃(μ-PPh₂)(CO)9}₂(μ₃:μ₃-C₄) with H+/H- or H₂ to Yield Penta- and Hexa-Nuclear Cluster Compounds | - |
dc.title.alternative | Reactions of {Ru(3)(mu-PPh(2))(CO)9}(2)(mu(3):mu(3)-C(4)) with H+/H- or H(2) to Yield Penta- and Hexa-Nuclear Cluster Compounds | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1071/CH01080 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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