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https://hdl.handle.net/2440/4357
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Type: | Journal article |
Title: | Two tetracobalt cluster complexes: Preparation and molecular structures of Co₄(μ-dppm)₂(μ-CO)₃(CO)₅ and CO₄(μ-CO)₃(CO)₆(η-C₆H₆) |
Other Titles: | Two tetracobalt cluster complexes: Preparation and molecular structures of Co(4)(mu-dppm)(2)(mu-CO)(3)(CO)(5) and CO(4)(mu-CO)(3)(CO)(6)(eta-C(6)H(6)) |
Author: | Bruce, M. Carty, A. Ellis, B. Low, P. Skelton, B. White, A. Udachin, K. Zaitseva, N. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 2001; 54(4):277-281 |
Publisher: | C S I R O Publishing |
Issue Date: | 2001 |
ISSN: | 0004-9425 1445-0038 |
Statement of Responsibility: | Michael I. Bruce, Arthur J. Carty, Benjamin G. Ellis, Paul J. Low, Brian W. Skelton, Allan H. White, Konstantin A. Udachin and Natasha N. Zaitseva |
Abstract: | The crystal and molecular structures of the title complexes (1) and (2) are described. Each contains a Co4 tetrahedron, one face of which is edge-bridged by three μ-CO ligands. In (1), a pair of mutually orthogonal Co-Co bonds are bridged by the two dppm (dppm = bis(diphenylphosphino)methane) ligands. The structure of the benzene complex was determined at 153 and 300 K; as with other arene-Co4 clusters, the η6-benzene ligand sits on the apical (i.e. non-CO-bridged) Co atom. |
Rights: | © CSIRO 2001 |
DOI: | 10.1071/CH01077 |
Published version: | http://www.publish.csiro.au/index.cfm?paper=CH01077 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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