Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4377
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| Type: | Journal article |
| Title: | Crystal and molecular structure of t-butylisocyanide-undecacarbonyl-tetrahydrido-tetraruthenium, Ru4(µ-H)4(CO)11(CNBut) |
| Other Titles: | Crystal and molecular structure of t-butylisocyanide-undecacarbonyl-tetrahydrido-tetraruthenium, Ru4(mu-H)4(CO)11(CNBut) |
| Author: | Bruce, M. Schulz, M. Tiekink, E. |
| Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1997; 50(9):879-882 |
| Publisher: | CSIRO Publishing |
| Issue Date: | 1997 |
| ISSN: | 0004-9425 |
| Statement of Responsibility: | Michael I. Bruce, Michael Schulz and Edward R. T. Tiekink |
| Abstract: | <jats:p> The crystal and molecular structures of Ru4(µ-H)4(CO)11(CNBut) (2), obtained with Ru4(µ- H)4(CO)10(CNBut)2 by hydrogenation of Ru5(µ5-CNBut)(CO)14(CNBut) (1), have been determined. Crystals of (2) are monoclinic, space group P 21/c, with a 12·349(1), b 11·627(3), c 17·0222(7) Å, β 105·785(4)°, V 2351·9(6) Å3 and Z 4. The structure was solved by direct methods and refined using 4478 reflections to final R 0·028(Rw0·033). An improved procedure for the preparation of (1) in 35–40% yields is also described.</jats:p> |
| Rights: | © CSIRO 1997 |
| DOI: | 10.1071/C97092 |
| Published version: | http://dx.doi.org/10.1071/c97092 |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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