Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/4392
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Hall, B. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 1996 | - |
dc.identifier.citation | Australian Journal of Chemistry: an international journal for chemical science, 1996; 49(9):1019-1021 | - |
dc.identifier.issn | 0004-9425 | - |
dc.identifier.uri | http://hdl.handle.net/2440/4392 | - |
dc.description.abstract | <jats:p>The reaction between Ru3(CO)12 and Ni{η1,η2-C5H5C2(CO2Me)2}Cp afforded orange Ru2{μ-η1,O:η2-C(CO2Me)=CHC(O) Ome }(CO)4Cp(43%) as the only isolable complex. An X-ray structure determination showed that a C(CO2Me)=CHC(O) OMe ligand bridges an Ru-Ru bond [2.7744(9) Ǻ] via a μ-η1:η2-vinyl interaction and by coordination of one of the ester CO groups [ Ru -O 2.148(2) Ǻ]. One ruthenium atom bears three terminal CO ligands and the other ruthenium atom has one CO ligand and an η5-C5H5 group. In the reaction, transfer of Cp and the vinyl group (from the bicyclo [2.2.1]hepta-2,5-dienyl ligand originally present) from nickel to ruthenium has occurred. </jats:p> | - |
dc.language.iso | en | - |
dc.publisher | CSIRO Publishing | - |
dc.rights | © CSIRO 1996 | - |
dc.source.uri | http://dx.doi.org/10.1071/ch9961019 | - |
dc.title | Cleavage of a bicyclo[2.2.1]hepta-2,5-dienyl ligand during transfer from nickel to ruthenium. X-ray structure of Ru2{m-h1, O:h2-C(CO2Me)=CHC(O)OMe} (CO)4Cp | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1071/CH9961019 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.