Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4533
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| Type: | Journal article |
| Title: | Cleavage of 1,4-diphenylbuta-1,3-diyne on a ruthenium-cobalt cluster: synthesis and molecular structure of Co2Ru3(m4-C2Ph)(m3-C2Ph)(m3-C2Ph)(m-dppm)(m-CO)2(CO)9 |
| Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
| Citation: | Journal of Cluster Science: including nanoclusters and nanoparticles, 1996; 7(2):109-119 |
| Publisher: | Springer Science and Business Media LLC |
| Issue Date: | 1996 |
| ISSN: | 1040-7278 1572-8862 |
| Statement of Responsibility: | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
| Abstract: | The reaction between Ru3(mgr3-ngr2-PhC2C=CPh)(mgr-dppm)(CO)8 and Co2(CO)8 afforded dark red Co2Ru3(mgr4-C2Ph)(mgr3-C2Ph)(mgr-dppm)(mgr-CO)2(CO)9, shown by an X-ray structure determination to contain a strongly twisted Co2Ru3 bow-tie cluster (central Co), to which two PhC2 units derived from cleavage of the original diyne are attached. One a these is strongly interacting with four metal atoms, the other being attached in the familiar ngr1,2ngr2-mode. The dppm ligand remains bridging two of the Ru atoms. |
| Keywords: | Alkynyl bow-tie cluster cobalt diyne cleavage ruthenium |
| DOI: | 10.1007/BF01166051 |
| Published version: | http://dx.doi.org/10.1007/bf01166051 |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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