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https://hdl.handle.net/2440/4570
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DC Field | Value | Language |
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Ke, M. | - |
dc.contributor.author | Kelly, B. | - |
dc.contributor.author | Low, P. | - |
dc.contributor.author | Smith, M. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 1999 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 1999; 599(2):184-201 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/2440/4570 | - |
dc.description.abstract | Reactions of [Ru(=C=C=C=CH2)(PR3)2Cp]+ (R=Ph or OMe) with arylimines ArN=CH(C6H4R) afford either substituted quinolines, Ru{CCC9H4RN(Ar)}(PR3)2Cp, by attack of the terminal carbon of the butatrienylidene ligand at the imine carbon, followed by C-C bond formation between the ortho carbon of the N-aryl group and Cγ of the unsaturated carbene, or 1-azabuta-1,3-dienyl complexes, formed by cycloaddition of the N=CH group to Cγ=Cδ of the carbene, followed by opening of the resulting four-membered ring. Some product dependence on the nature of the substituents in the N- and C-aryl groups is found. The N atoms in the products are strongly basic, being readily protonated, methylated or aurated. The molecular structures of nine complexes are reported, together with that of a new modification of RuCl{P(OMe)3}2Cp. © 1999 Elsevier Science S.A. | - |
dc.language.iso | en | - |
dc.publisher | Elsevier BV | - |
dc.source.uri | http://dx.doi.org/10.1016/s0022-328x(99)00456-8 | - |
dc.title | Syntheses of complexes containing substituted 4-ethynylquinolines or 1-azabuta-1,3-dienes by addition of imines to a cationic butatrienylidene-ruthenium complex | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1016/S0022-328X(99)00456-8 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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