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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4654
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dc.contributor.authorBruce, M.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.contributor.authorZaitseva, N.-
dc.date.issued1999-
dc.identifier.citationJournal- Chemical Society Dalton Transactions, 1999; 13-14(1):13-14-
dc.identifier.issn0300-9246-
dc.identifier.issn1364-5447-
dc.identifier.urihttp://hdl.handle.net/2440/4654-
dc.description.abstractThermolysis of Ru3(µ3-C2H2)(µ-CO)(CO)9 1 (50 °C, 6 h) has given Ru5(µ4-CHCHCCH2)(CO)15 3 and Ru6(µ-H)(µ4-C)(µ4-CCMe)(µ-CO)(CO)16 4, both characterised by X-ray crystallography; in 3, coupling of two ethyne molecules occurred, likely with prior isomerisation of one to vinylidene, whereas in 4, two molecules of ethyne disproportionate to carbide and methylethynyl.-
dc.description.statementofresponsibilityMichael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva-
dc.language.isoen-
dc.publisherRoyal Society of Chemistry (RSC)-
dc.source.urihttp://www.rsc.org/Publishing/Journals/DT/article.asp?doi=a807781i-
dc.titleCoupling and disproportionation reactions of ethyne on ruthenium carbonyl clusters: Molecular structures of Ru5(m4-CHCHCCH2)(CO)15 and Ru6(m-H)(m4-C)(m4-CCMe)(m-CO)(CO)16-
dc.typeJournal article-
dc.identifier.doi10.1039/a807781i-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 2
Chemistry publications

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