Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/4677
Citations | ||
Scopus | Web of ScienceĀ® | Altmetric |
---|---|---|
?
|
?
|
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Hall, B. | - |
dc.contributor.author | Zaitseva, N. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 1998 | - |
dc.identifier.citation | Journal- Chemical Society Dalton Transactions, 1998; (11):1793-1803 | - |
dc.identifier.issn | 0300-9246 | - |
dc.identifier.issn | 1364-5447 | - |
dc.identifier.uri | http://hdl.handle.net/2440/4677 | - |
dc.description.abstract | A synthesis of neutral vinylideneruthenium complexes [RuCl(CCHR)(PPh3)(-C5Me5)] (R = Ph, But or SiMe3) from [RuCl(PPh3)2(-C5Me5)] and 1-alkynes has been developed. This takes advantage of the presence of two bulky ligands (PPh3 and C5Me5), which results in displacement of one PPh3 ligand (rather than chloride) and concomitant isomerisation of the 1-alkyne to vinylidene ligands. The vinylidene complexes undergo facile loss of HCl on treatment with NaOMe in the presence of a 2e donor ligand (L) to give the neutral acetylide complexes [Ru(CCR)L(PPh3)(-C5Me5)] [R = Ph, L = PPh3, CO, O2 or dppm-P; R = But, L = PPh3, CO, C2H4, dppe-P, C2(PPh2)2-P, S2, P(OMe)3 or AsPh3]; the complexes [Ru(CCBut)(L2)(-C5Me5)] [L2 = dppm or PPh2CH CHPPh2] and [Ru(S2CCCBut)(PPh3)(-C5Me5)] were also obtained. Crystal structure determinations were carried out on eleven of the complexes. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Ben C. Hall, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry (RSC) | - |
dc.source.uri | http://dx.doi.org/10.1039/a800871j | - |
dc.title | Preparation and reactions of some neutral pentamethylcyclopentadienylruthenium vinylidene complexes | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/a800871j | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.