Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/47524
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Type: | Journal article |
Title: | (2S,4'R,5'R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3- dioxolan-4-ylmethyl)-5-phenylpent-4-enoate |
Author: | Fox, David J. Pedersen, Daniel Sejer Warren, Stuart |
Citation: | Acta Crystallographica Section E: Structure Reports Online, 2008; 64 (2):o530 |
Publisher: | International Union of Crystallography |
Issue Date: | 2008 |
ISSN: | 1600-5368 |
School/Discipline: | School of Chemistry and Physics : Chemistry |
Statement of Responsibility: | David J. Fox ; Daniel Sejer Pedersen and Stuart Warren |
Abstract: | The title compound, C₂₇H₃₀O₆, was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intramolecular edge-to-face C-H… π contact with an interplanar angle of 56.4° and a H…centroid distance of 3.03 Å. |
DOI: | 10.1107/S1600536808002651 |
Appears in Collections: | Chemistry and Physics publications |
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