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https://hdl.handle.net/2440/51875
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Type: | Journal article |
Title: | The Bis-{Co₂(μ-dppm)(CO)₄} adduct of dimethyl hex-3-en-1,5-diyne-1,6-dicarboxylate |
Other Titles: | The bis-{Co-2(mu-dppm)(CO)(4)} adduct of dimethyl hex-3-en-1,5-diyne-1,6-dicarboxylate |
Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2008; 634(6-7):1102-1105 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2008 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Allan H. White, Natasha N. Zaitseva |
Abstract: | <jats:title>Abstract</jats:title><jats:p>The synthesis and structural characterization of a bis‐dicobalt derivative of dimethyl hex‐3‐en‐1,5‐diyne‐1,6‐dicarboxylate, [{Co<jats:sub>2</jats:sub>(μ‐dppm)(CO)<jats:sub>4</jats:sub>}<jats:sub>2</jats:sub>(μ:μ‐MeO<jats:sub>2</jats:sub>CC<jats:sub>2</jats:sub>CH=CHC<jats:sub>2</jats:sub>CO<jats:sub>2</jats:sub>Me)]·2CHCl<jats:sub>3</jats:sub> (<jats:bold>1</jats:bold>) is described, permitting, in the context of previous related studies, comparison of the effects of progressive substitution of the ethene hydrogen atoms by C≡C·SiMe<jats:sub>3</jats:sub> groupings.</jats:p> |
Keywords: | Cobalt Crystal structure Alkene complexes Alkyne complexes Organometallic compounds |
DOI: | 10.1002/zaac.200800021 |
Published version: | http://dx.doi.org/10.1002/zaac.200800021 |
Appears in Collections: | Aurora harvest Chemistry publications |
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