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https://hdl.handle.net/2440/53498
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Type: | Journal article |
Title: | Reactions of alkynyl-ruthenium complexes with the ketene dithioacetal, (MeS)₂C═C(CN)₂ |
Other Titles: | Reactions of alkynyl-ruthenium complexes with the ketene dithioacetal, (MeS)(2)C=C(CN)(2) |
Author: | Armitt, D. Bruce, M. Skelton, B. White, A. |
Citation: | Organometallics, 2008; 27(14):3556-3563 |
Publisher: | Amer Chemical Soc |
Issue Date: | 2008 |
ISSN: | 0276-7333 1520-6041 |
Statement of Responsibility: | David J. Armitt, Michael I. Bruce, Brian W. Skelton and Allan H. White |
Abstract: | Reactions of several alkynyl-ruthenium complexes with the ketene dithioacetal (MeS)2C=C(CN)2 (2) are described. The first examples of metalated 6-alkylthio-6-azafulvenes, Ru(C=CRC-(SMe)=C(CN)C=N(SMe)) (PPh3)Cp [R = Ph (5a), Fc (5b)], were obtained from Ru(C≡CR)(PPh3)2Cp, while Ru(C≡CPh)(CO) (PPh3)Cp gave dienyl complexes Ru(C(SMe)=CPhC(SMe)=C(CN)2 }(CO)-(PPh3)nCp [n = 1 (8), 0 (9)]. Yields of the azafulvenes were increased under conditions conducive to radical formation. The reaction between 5 and Ru(C≡CC≡CPh)(PPh3)2Cp afforded the alkynyl-dienyl Ru{C(SMe)=C(C≡CPh)C(SMe)=C(CN) 2)(PPh3)Cp (11) and the dienynyl Ru(C≡CC(SMe)=CPhC- (SMe)=C(CN)2}(PPh3)2Cp (12), formed by formal insertion of either C≡C triple bond into one C-S bond. The reaction of Ru(C≡CPh)(PPh3)2Cp with dimethyl 2,3-dicyanofumarate (3) afforded diastereomers of the η3-dienyl complex Ru (η3-C(CN)(CO2Me)CPhC=C(CN)(CO2Me)} (PPh3)Cp (13). XRD structural determinations of 5a, 8, 9, 11, and one diastereomer of 13 are reported. © 2008 American Chemical Society. |
Rights: | Copyright © 2008 American Chemical Society |
DOI: | 10.1021/om7011437 |
Published version: | http://dx.doi.org/10.1021/om7011437 |
Appears in Collections: | Aurora harvest 5 Chemistry and Physics publications |
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