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https://hdl.handle.net/2440/53504
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Type: | Journal article |
Title: | The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands |
Author: | Carruthers, C. Ronson, T. Sumby, C. Westcott, A. Harding, L. Prior, T. Rizkallah, P. Hardie, M. |
Citation: | Chemistry: A European Journal, 2008; 14(33):10286-10296 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2008 |
ISSN: | 0947-6539 1521-3765 |
Statement of Responsibility: | Christopher Carruthers, Tanya K. Ronson, Christopher J. Sumby, Aleema Westcott, Lindsay P. Harding, Timothy J. Prior, Pierre Rizkallah and Michaele J. Hardie |
Abstract: | A series of clathrate and metal complexes with cyclotriveratrylene-like molecular host ligands show a similar dimeric homomeric inclusion motif in which a ligand arm of one host is the intra-cavity guest of another and vice versa. This "hand-shake" motif is found in the trinuclear transition metal complex [Cu(3)Cl(6)(1)]CH(3)CN1.5 H(2)O in which 1 is tris(4-[2,2',6',2''-terpyridyl]benzyl)cyclotriguaiacylene; in the self-included M(4)L(4) tetrahedral metallo-supramolecular assembly [Ag(4)(2)(4)] (BF(4))(4) in which 2 is tris-(2-quinolylmethyl)cyclotriguaiacylene; in the 1D coordination chains [Ag(4)]ReO(4) CH(3)CN and [Ag(5)]SbF(6)3 DMFH(2)O in which 4 is tris(1H-imidazol-1-yl)cyclotriguaiacylene and 5 is tris{4-(2-pyridyl)benzyl}cyclotriguaiacylene; and in the acetone clathrate of tris{4-(2-pyridyl)benzyl-amino}cyclotriguaiacylene. Clathrates of ligands 2 and 5 do not show the same dimeric motif, although 2 has an extended homomeric inclusion motif that gives a hexagonal network. |
Description: | The definitive version may be found at www.wiley.com |
DOI: | 10.1002/chem.200801264 |
Published version: | http://dx.doi.org/10.1002/chem.200801264 |
Appears in Collections: | Aurora harvest 5 Chemistry and Physics publications Environment Institute publications |
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