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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/61176
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dc.contributor.authorBruce, M.-
dc.contributor.authorScoleri, N.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.date.issued2010-
dc.identifier.citationJournal of Organometallic Chemistry, 2010; 695(10-11):1561-1568-
dc.identifier.issn0022-328X-
dc.identifier.issn1872-8561-
dc.identifier.urihttp://hdl.handle.net/2440/61176-
dc.description.abstractLithiated Ru(C{triple bond, long}CC{triple bond, long}CH)(dppe)Cp* reacts with polyfluoroaromatic compounds C6F5X (X = F, OMe, CN, NO2) and C10F8 to give novel polyfluoroaryldiynyls end-capped with the Ru(dppe)Cp* group. Addition of tcne to Ru(C{triple bond, long}CC{triple bond, long}CC6F5)(dppe)Cp* afforded the butadienynyl Ru{C{triple bond, long}CC[{double bond, long}C(CN)2]C(C6F5){double bond, long}C(CN)2}(dppe)Cp*, while protonation with HBF4·OEt2 resulted in cycloaddition to give [1,3-{Cp*(dppe)RuC{triple bond, long}C}2{μ-C4H(C6F5)2}]BF4. XRD molecular structures of complexes with X = F, CN, OMe and the C10F7 derivative are reported. © 2010 Elsevier B.V. All rights reserved.-
dc.description.statementofresponsibilityMichael I. Bruce, Nancy Scoleri, Brian W. Skelton, Allan H. White-
dc.language.isoen-
dc.publisherElsevier Science Sa-
dc.rightsCopyright © 2010 Elsevier B.V. All rights reserved.-
dc.source.urihttp://dx.doi.org/10.1016/j.jorganchem.2010.03.017-
dc.subjectAlkynyl-
dc.subjectDiynyl-
dc.subjectRuthenium-
dc.subjectFluoroaromatic-
dc.subjectCrystal structure-
dc.titleSyntheses and molecular structures of some polyfluoroaryldiynyl-ruthenium complexes-
dc.typeJournal article-
dc.identifier.doi10.1016/j.jorganchem.2010.03.017-
dc.relation.grantARC-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest
Chemistry publications

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