Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/61220
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hodyl, J. | - |
dc.contributor.author | Lincoln, S. | - |
dc.contributor.author | Wainwright, K. | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2010; 68(3-4):261-270 | - |
dc.identifier.issn | 1388-3127 | - |
dc.identifier.issn | 0923-0750 | - |
dc.identifier.uri | http://hdl.handle.net/2440/61220 | - |
dc.description.abstract | A series of cyclen (1,4,7,10-tetraazacyclododecane) derived molecular receptors for aromatic oxoanions, that are activated by complexation with Cd(II), have been covalently linked to 3-(glycidoxy)propyl-functionalised silica gel (70–230 mesh). These immobilised receptor complexes are highly effective for the sequestration of o-hydroxybenzoates and 2-naphthoate from aqueous solution, achieving a >80% saturation level by stirring the material in the aqueous solution for 1 h at pH 7.00 and 298 K. Examination of the uptake levels of a variety of different benzoates and naphthoates suggests that the retention mechanism involves a combination of classical hydrogen bonding and non-classical, water mediated, O–H···π hydrogen bonding. Contrary to expectations, attachment of hydroxy terminated polyether chains to the periphery of the receptor complex diminished the level of uptake. | - |
dc.description.statementofresponsibility | Jozef A. Z. Hodyl, Stephen F. Lincoln and Kevin P. Wainwright | - |
dc.language.iso | en | - |
dc.publisher | Kluwer Academic Publ | - |
dc.rights | © Springer Science+Business Media B.V. 2010 | - |
dc.source.uri | http://dx.doi.org/10.1007/s10847-010-9782-8 | - |
dc.subject | Inclusion complex | - |
dc.subject | Hydroxybenzoates | - |
dc.subject | Naphthoates | - |
dc.subject | Cyclen derivatives | - |
dc.subject | Silica attachment | - |
dc.title | Silica-attached molecular receptor complexes for benzoates and naphthoates | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1007/s10847-010-9782-8 | - |
dc.relation.grant | ARC | - |
pubs.publication-status | Published | - |
Appears in Collections: | Aurora harvest 5 Chemistry publications Environment Institute publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.