Adelaide Research & Scholarship
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https://hdl.handle.net/2440/61533
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| Type: | Journal article |
| Title: | Biomimetic synthesis of polycyclic polyprenylated acylphloroglucinol natural products isolated from Hypericum papuanum |
| Author: | George, J. Hesse, M. Baldwin, J. Adlington, R. |
| Citation: | Organic Letters, 2010; 12(15):3532-3535 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2010 |
| ISSN: | 1523-7060 1523-7052 |
| Statement of Responsibility: | Jonathan H. George, Micha D. Hesse, Jack E. Baldwin and Robert M. Adlington |
| Abstract: | Biomimetic syntheses of three polycylic polyprenylated acylphloroglucinol natural products isolated from Hypericum papuanum, ialibinone A, ialibinone B, and hyperguinone B, have been accomplished by selective oxidative cyclizations of the proposed biosynthetic precursor 5, which was synthesized from phloroglucinol in three steps. |
| Keywords: | Hypericum Phloroglucinol Biological Products Molecular Structure Cyclization Oxidation-Reduction Polycyclic Aromatic Hydrocarbons |
| Rights: | Copyright © 2010 American Chemical Society |
| DOI: | 10.1021/ol101380a |
| Published version: | http://dx.doi.org/10.1021/ol101380a |
| Appears in Collections: | Aurora harvest Chemistry publications |
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