Adelaide Research & Scholarship
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https://hdl.handle.net/2440/70263
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| Type: | Journal article |
| Title: | Crystalline covalent organic frameworks with hydrazone linkages |
| Author: | Uribe-Romo, F. Doonan, C. Furukawa, H. Oisaki, K. Yaghi, O. |
| Citation: | Journal of the American Chemical Society, 2011; 133(30):11478-11481 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2011 |
| ISSN: | 0002-7863 1520-5126 |
| Statement of Responsibility: | Fernando J. Uribe-Romo, Christian J. Doonan, Hiroyasu Furukawa, Kounosuke Oisaki, and Omar M. Yaghi |
| Abstract: | Condensation of 2,5-diethoxyterephthalohydrazide with 1,3,5-triformylbenzene or 1,3,5-tris(4-formylphenyl)benzene yields two new covalent organic frameworks, COF-42 and COF-43, in which the organic building units are linked through hydrazone bonds to form extended two-dimensional porous frameworks. Both materials are highly crystalline, display excellent chemical and thermal stability, and are permanently porous. These new COFs expand the scope of possibilities for this emerging class of porous materials. |
| Keywords: | Organic Chemicals Hydrazones Benzene Derivatives Crystallography, X-Ray Surface Properties Porosity Models, Molecular |
| Rights: | Copyright © 2011 American Chemical Society |
| DOI: | 10.1021/ja204728y |
| Published version: | http://dx.doi.org/10.1021/ja204728y |
| Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
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