Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/71102
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Structural studies of some compounds containing C2 fragments attached to various metal-ligand end-groups |
Author: | Bruce, M. Gaudio, M. Hall, B. Nicholson, B. Perkins, G. Skelton, B. White, A. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2011; 637(9):1207-1212 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2011 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Maryka Gaudio, Benjamin C. Hall, Brian K. Nicholson, Gary J. Perkins, Brian W. Skelton and Allan H. White |
Abstract: | The preparation, characterisation and single-crystal XRD molecular structure determinations of four complexes containing –CC–MLn end-groups, namely Ru{C≡CFc′(I)}(dppe)Cp (1), the vinylidene [Os(=C=CH2)(PPh3)2Cp]PF6 (2), trans-Pt(C≡CC6H4-4-C≡CPh){C≡CC6H4-4-C2Ph[Co2(μ-dppm)(CO)4]}(PPh3)2 (3), and C6H4{μ3-C2[AuRu3(CO)9(PPh3)]}2-1,4 (4) are reported. In these compounds a range of –CC– environments is found, extending from the σ-bonded alkynyl group in 1 to examples where the C2 unit interacts with either a proton (in vinylidene 2), by bridging a dicobalt carbonyl moiety (in 3) or the AuRu3 cluster in 4. Changes in geometry are rationalised by considering the various bonding modes. |
Keywords: | C2 ligands metal complexes XRD structure Ruthenium Osmium Platinum |
Rights: | Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/zaac.201100099 |
Grant ID: | ARC |
Published version: | http://dx.doi.org/10.1002/zaac.201100099 |
Appears in Collections: | Aurora harvest 5 Chemistry and Physics publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.