Adelaide Research & Scholarship
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https://hdl.handle.net/2440/71189
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| Type: | Journal article |
| Title: | Nucleophilic properties of Ru(C CH)(dppe)Cp*: Synthesis and structure of Ru{c-C=CArC(O)C(O)O}(dppe)Cp* [Ar=2,4-(NO2)2C6H3] |
| Author: | Bruce, M. Morris, J. Parker, C. Skelton, B. |
| Citation: | Journal of Organometallic Chemistry, 2011; 696(21):3292-3295 |
| Publisher: | Elsevier Science Sa |
| Issue Date: | 2011 |
| ISSN: | 0022-328X 1872-8561 |
| Statement of Responsibility: | Michael I. Bruce, Jonathan C. Morris, Christian R. Parker and Brian W. Skelton |
| Abstract: | The complex Ru{c-CCArC(O)C(O)O}(dppe)Cp* [Ar = 2,4-(NO 2)2C6H3] 2, containing a dihydrofuran-3,4-dione ligand, was obtained from a reaction between the strong nucleophile Ru(CCH)(dppe)Cp* 1 and bis(2,4-dinitrophenyl) oxalate. The X-ray determined molecular structure of 2 is reported, together with a plausible route for its formation. © 2011 Elsevier B.V. All rights reserved. |
| Keywords: | Ruthenium Metalla-alkynyl ketone Cyclisation Dihydrofuran X-ray structure |
| Rights: | © 2011 Elsevier B.V. All rights reserved. |
| DOI: | 10.1016/j.jorganchem.2011.07.020 |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1016/j.jorganchem.2011.07.020 |
| Appears in Collections: | Aurora harvest 5 Chemistry publications |
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