Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/79477
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dc.contributor.author | Bloch, W. | - |
dc.contributor.author | Doonan, C. | - |
dc.contributor.author | Sumby, C. | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | CrystEngComm, 2013; 15(45):9663-9671 | - |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.uri | http://hdl.handle.net/2440/79477 | - |
dc.description | First published online 23 Aug 2013 | - |
dc.description.abstract | Here we report two new flexible MOFs based on a bis-pyrazolylmethane 'hinged' link design that favours the formation of two distinct structural nodes within the resulting 2-D and 3-D structures. The less sterically demanding ligand H₂bcppm affords a 2-D layered MOF, {Cu₂[Cuˡˡ(NO₃)₂(bcppm)₂](DMF)₂}•2DMF (1), constructed from copper(II) paddlewheel and mononuclear octahedral copper(II) nodes. The use of a more sterically encumbered tetramethyl analogue H₂bcpdmpm induces a dramatic twisting of the ligand backbone that yields a 3-D MOF{Cu₄[Cuˡ(bcpdmpm)₂]₂(EtOH)₂(H₂O)₂}(NO₃)₂•12DMF (2) formed from a very similar mix of nodes, specifically copper(II) paddlewheel clusters and mononuclear tetrahedrally coordinated copper(I) centres. Herein we describe the crystal structures, solid-state flexibility, and gas adsorption properties of both materials. | - |
dc.description.statementofresponsibility | Witold M. Bloch, Christian J. Doonan and Christopher J. Sumby | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry | - |
dc.rights | © The Royal Society of Chemistry 2013 | - |
dc.source.uri | http://dx.doi.org/10.1039/c3ce41244j | - |
dc.title | Using hinged ligands to target structurally flexible copper(II) MOFs | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/C3CE41244J | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FT100100400 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FT0991910 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bloch, W. [0000-0003-1084-1287] | - |
dc.identifier.orcid | Sumby, C. [0000-0002-9713-9599] | - |
Appears in Collections: | Aurora harvest 4 Chemistry and Physics publications Environment Institute publications |
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File | Description | Size | Format | |
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hdl_79477.pdf | Published version | 1.29 MB | Adobe PDF | View/Open |
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