Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/84480
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Type: | Journal article |
Title: | A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO₂ |
Other Titles: | A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO(2) |
Author: | Burgun, A. Crees, R. Cole, M. Doonan, C. Sumby, C. |
Citation: | Chemical Communications, 2014; 50(79):11760-11763 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2014 |
ISSN: | 1364-548X 1364-548X |
Statement of Responsibility: | Alexandre Burgun, Rachel S. Crees, Marcus L. Cole, Christian J. Doonan and Christopher J. Sumby |
Abstract: | A new MOF, [Zn4O{Cu(L)2}2] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L)2] NHC linkers. MOF 1 possesses tetrahedral Zn4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L)2] linkers, and 14 A 1-D pore channels lined with [Cu(L)2] moieties that catalyse the hydroboration of CO2. |
Description: | Includes supplementary information |
Rights: | This journal is © The Royal Society of Chemistry 2014 |
DOI: | 10.1039/C4CC04761C |
Grant ID: | http://purl.org/au-research/grants/arc/FT100100400 http://purl.org/au-research/grants/arc/FT0991910 |
Published version: | http://dx.doi.org/10.1039/c4cc04761c |
Appears in Collections: | Aurora harvest 2 Chemistry and Physics publications |
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hdl_84480.pdf | 1.57 MB | Adobe PDF | View/Open |
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