Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/96413
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Type: | Journal article |
Title: | Hetero-bimetallic metal-organic polyhedra |
Author: | Teo, J. Coghlan, C. Evans, J. Tsivion, E. Head-Gordon, M. Sumby, C. Doonan, C. |
Citation: | Chemical Communications, 2016; 52(2):276-279 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2016 |
ISSN: | 1364-548X 1364-548X |
Statement of Responsibility: | Jesse M. Teo, Campbell J. Coghlan, Jack D. Evans, Ehud Tsivion, Martin Head-Gordon, Christopher J. Sumby, and Christian J. Doonan |
Abstract: | Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1). |
Description: | First published online 26 Oct 2015 |
Rights: | © the author. This journal is ©The Royal Society of Chemistry 2015. |
DOI: | 10.1039/c5cc08336b |
Grant ID: | http://purl.org/au-research/grants/arc/FT100100400 http://purl.org/au-research/grants/arc/FT0991910 |
Published version: | http://dx.doi.org/10.1039/c5cc08336b |
Appears in Collections: | Aurora harvest 7 Chemistry publications |
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hdl_96413.pdf | Accepted version | 663.71 kB | Adobe PDF | View/Open |
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