Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/102218
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Polypyrrole shell@3D-Ni metal core structured electrodes for high-performance supercapacitors |
Author: | Chen, G. Su, Y. Kuang, P. Liu, Z. Chen, D. Wu, X. Li, N. Qiao, S. |
Citation: | Chemistry: A European Journal, 2015; 21(12):4614-4621 |
Publisher: | Wiley |
Issue Date: | 2015 |
ISSN: | 0947-6539 1521-3765 |
Statement of Responsibility: | Gao-Feng Chen, Yu-Zhi Su, Pan-Yong Kuang, Zhao-Qing Liu, Dao-Yi Chen, Xu Wu, Nan Li and Shi-Zhang Qiao |
Abstract: | Three-dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high-performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D-Ni-core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as-prepared material exhibits a high specific capacitance (726 F g⁻¹ at a charge/discharge rate of 1 A g⁻¹), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g⁻¹), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s⁻¹. Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as-prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg⁻¹) and superior long-term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). |
Keywords: | core-shell structures electrochemistry nickel polypyrrole supercapacitors |
Rights: | © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/chem.201405976 |
Published version: | http://dx.doi.org/10.1002/chem.201405976 |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.