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https://hdl.handle.net/2440/112065
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dc.contributor.author | Coghlan, C. | - |
dc.contributor.author | Campi, E. | - |
dc.contributor.author | Batten, S. | - |
dc.contributor.author | Jackson, W. | - |
dc.contributor.author | Hearn, M. | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Polyhedron, 2018; 144:187-197 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.issn | 1873-3719 | - |
dc.identifier.uri | http://hdl.handle.net/2440/112065 | - |
dc.description | Available online 9 February 2018 | - |
dc.description.abstract | Reactions of ortho-, para- and substituted meta-xylenyl bridged bis(tacn) ligands with two or three molar equivalents of Zn(NO3)2·6H2O at pH 5.0 in the presence of NaClO4 or NH4PF6 resulted in the formation of a range of crystalline zinc complexes. In the presence of perchlorate counter ions the Lpx and Lphx ligands gave rise to dinuclear Zn2+ coordination complexes [Zn2Cl2(Lpx)(H2O)2](ClO4)2(H2O) and [Zn2Cl2(Lphx)(H2O)2](ClO4)2(H2O)2 respectively, which formed infinite 1D polymeric chains. In contrast, in the presence of the hexafluorophosphate counter ion, the Lnix ligand formed a unique tetranuclear Zn2+ complex, [Zn2Cl2(Lnix)(H2O)3](Cl)(PF6)2(H2O)4, the Lcax ligand formed an octanuclear complex [Zn8Cl4(Lcax)4(H2O)10](PF6)6.7(NO3)1.3(H2O)3.3, whilst the Lox ligand formed a mononuclear sandwich structure, [Zn(Lox)](PF6)2(H2O). The protonated metal-free Lpx ligand crystallised as [H4(Lpx)](NO3)2(PF6)(H2O)2 with the stacked ligand cations forming a hydrogen-bonded network. These structural attributes provide an explanation for the significant differences in binding behaviour of recombinant N-terminally tagged proteins with the corresponding Zn2+-azamacrocyclic complexes, compared to the analogous Cu2+- or Ni2+-azamacrocyclic complexes, when immobilised onto support materials and used as immobilised metal affinity chromatographic (IMAC) adsorbents. | - |
dc.description.statementofresponsibility | Campbell J. Coghlan, Eva M. Campi, Stuart R. Batten, W. Roy Jackson, Milton T.W. Hearn | - |
dc.language.iso | en | - |
dc.publisher | Elsevier | - |
dc.rights | © 2018 Elsevier Ltd. All rights reserved. | - |
dc.source.uri | http://dx.doi.org/10.1016/j.poly.2018.01.013 | - |
dc.subject | Zinc(II) aza-macrocyclic complexes; crystal structures; xylenyl linkers; IMAC separations; bis(tacn) ligands | - |
dc.title | Impact of the substitution pattern of xylyl-bridged 1,4-bis(1,4,7-triazacyclononane) ligands on the crystal structures of their zinc(II) complexes and their ability to bind to N-terminally tagged proteins | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1016/j.poly.2018.01.013 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/LP0561064 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Coghlan, C. [0000-0003-1625-3216] | - |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
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