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https://hdl.handle.net/2440/119276
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Type: | Journal article |
Title: | Identification and quantitative analysis of 2-methyl-4-propyl-1,3-oxathiane in wine |
Author: | Chen, L. Capone, D. Jeffery, D. |
Citation: | Journal of Agricultural and Food Chemistry, 2018; 66(41):10808-10815 |
Publisher: | American Chemical Society |
Issue Date: | 2018 |
ISSN: | 0021-8561 1520-5118 |
Statement of Responsibility: | Liang Chen, Dimitra L. Capone and David W. Jeffery |
Abstract: | On the basis of the chemistry of wine and the co-occurrence of 3-sulfanylhexan-1-ol (3-SH) and acetaldehyde, we investigated the existence of 2-methyl-4-propyl-1,3-oxathiane (1) and identified the presence of a single detectable geometric isomer, cis-1, in wines for the first time. A stable isotope dilution assay (SIDA) using headspace-solid-phase microextraction (HS-SPME) and gas chromatography-mass spectrometry (GC-MS) was developed and validated, and used to quantitate cis-1 in a survey of wines, revealing a range from undetectable (limit of detection = 2.6 ng/L) to 460 ng/L. The odor detection threshold of 1 (using a standard comprising 85% cis-1 and 15% trans-1) in neutral white wine was determined to be 7.1 μg/L. Despite cis-1 not appearing above the determined sensory threshold in the studied wines, the findings demonstrated the presence of a new volatile sulfur compound with a strong correlation to 3-SH concentration ( r = 0.72), showing that cis-1 has potential implications for the fate of the important wine aroma compound 3-SH. |
Keywords: | 3-sulfanylhexan-1-ol polyfunctional thiol stable isotope dilution assay tropical fruit wine aroma |
Rights: | © 2018 American Chemical Society |
DOI: | 10.1021/acs.jafc.8b04027 |
Published version: | http://dx.doi.org/10.1021/acs.jafc.8b04027 |
Appears in Collections: | Agriculture, Food and Wine publications Aurora harvest 8 |
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