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https://hdl.handle.net/2440/125946
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Type: | Journal article |
Title: | Enhanced separation performance of a novel composite material GrO@MIL-101 for CO₂/CH₄ binary mixture |
Other Titles: | Enhanced separation performance of a novel composite material GrO@MIL-101 for CO(2)/CH(4) binary mixture |
Author: | Zhou, X. Huang, W. Miao, J. Xia, Q. Zhang, Z. Wang, H. Li, Z. |
Citation: | Chemical Engineering Journal, 2015; 266:339-344 |
Publisher: | Elsevier |
Issue Date: | 2015 |
ISSN: | 1385-8947 1873-3212 |
Statement of Responsibility: | Xin Zhou, Wenyu Huang, Jinpeng Miao, Qibin Xia, Zhijuan Zhang, Haihui Wang, Zhong Li |
Abstract: | A novel GrO@MIL-101 composite consisting of graphene oxide (GrO) and MIL-101(Cr) was synthesized, characterized and tested for separation of CO2/CH4 mixture. GrO@MIL-101 had higher BET surface area and better porosity than parent MIL-101. CO2 and CH4 isotherms were separately measured at different temperatures using a gravimetric method, and were fitted using the dual-site Langmuir–Freundlich (DSLF) model. The adsorption capacity of GrO@MIL-101 for CO2 was significantly improved over MIL-101, reaching 22.4 mmol g−1 at 25 bar and 298 K, much higher than traditional adsorbents and most other MOFs. The isotherms and selectivities of CO2/CH4 binary mixture were estimated using the ideal adsorbed solution theory (IAST). While calculated isotherms indicated CO2 was more favorably adsorbed on GrO@MIL-101 than CH4, the adsorption selectivity of GrO@MIL-101 composite was dramatically enhanced over pristine MIL-101. At 1.5 bar, the selectivity of GrO@MIL-101 for CO2/CH4 (10:90) mixture with a characteristic of natural gas was up to 32, which was more than three times of that of MIL-101. Isosteric heats of adsorption for CO2 and CH4 on GrO@MIL-101 were slightly above those on parent MIL-101. GrO@MIL-101 also displayed remarkable quasi-reversibility for CO2 adsorption, showing more than 95% desorption efficiency over five cycles. |
Keywords: | Graphene oxide (GrO; )MIL-101; GrO@MIL-101 composite; CO2/CH4 separation; selectivity |
Rights: | © 2014 Elsevier B.V. All rights reserved. |
DOI: | 10.1016/j.cej.2014.12.021 |
Published version: | http://dx.doi.org/10.1016/j.cej.2014.12.021 |
Appears in Collections: | Aurora harvest 4 Chemical Engineering publications |
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