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https://hdl.handle.net/2440/132365
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Type: | Journal article |
Title: | Rational design of Si@carbon with robust hierarchically porous custard-apple-like structure to boost lithium storage |
Author: | Xu, R. Wang, G. Zhou, T. Zhang, Q. Cong, H.P. Xin, S. Rao, J. Zhang, C. Liu, Y. Guo, Z. Yu, S.H. |
Citation: | Nano Energy, 2017; 39:253-261 |
Publisher: | Elsevier |
Issue Date: | 2017 |
ISSN: | 2211-2855 2211-3282 |
Statement of Responsibility: | Runtao Xu, Gang Wang, Tengfei Zhou, Qing Zhang, Huai-Ping Cong, Sen Xin, Juan Rao, Chaofeng Zhang, Yakun Liu, Zaiping Guo, Shu-Hong Yu |
Abstract: | In this work, we have developed a simple approach to rationally design and controllably synthesize custard-apple-like Si@N, O-dual-doped carbon with hierarchical porosity. This material delivers outstanding reversible capacity at high current density with good rate capability and a long cycling life of over 4000 cycles as an anode for Li-ion batteries. A detailed eletrochemical kinetic analysis reveals that the lithium ion charge storage partly depends on the capacitance-controlled behavior, with a high capacitive contribution up to 30.3% for the total capacity at 1 mV s⁻¹. The impressive eletrochemical performance demonstrates that the Si@mNOC anode has great potential to meet the challenges arising from the use of Si nanoparticles as anode for next-generation large-scale energy storage. |
Keywords: | N, O-dual doped carbon; custard-apple-like; hierarchical porous; silicon; long life cycling |
Rights: | © 2017 Elsevier Ltd. All rights reserved. |
DOI: | 10.1016/j.nanoen.2017.07.007 |
Grant ID: | http://purl.org/au-research/grants/arc/FT150100109 |
Published version: | http://dx.doi.org/10.1016/j.nanoen.2017.07.007 |
Appears in Collections: | Chemical Engineering publications |
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