Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/136703
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Type: | Journal article |
Title: | Microstructure and corrosion resistance of highly <111> oriented electrodeposited CoNiFe medium-entropy alloy films |
Author: | Huo, W. Wang, S. Fang, F. Tan, S. Kurpaska, L. Xie, Z. Kim, H.S. Jiang, J. |
Citation: | Journal of Materials Research and Technology, 2022; 20:1677-1684 |
Publisher: | Elsevier |
Issue Date: | 2022 |
ISSN: | 2238-7854 2214-0697 |
Statement of Responsibility: | Wenyi Huo, Shiqi Wang, Feng Fang, Shuyong Tan, Łukasz Kurpaska, Zonghan Xie, Hyoung Seop Kim, Jianqing Jiang |
Abstract: | The medium-entropy alloy is a newly intriguing material showing superb properties. A simple, one-step method was developed to electrodeposit CoNiFe medium-entropy alloy films from a sulfate and citrate bath. The microstructure and corrosion resistance were investigated in CoNiFe films with varying deposition current densities. It shows the facecentered cubic structure with a <111> preferential orientation. HRTEM-EDS observations further show information on the nanostructure and element distribution. The films exhibit a strong corrosion resistance in 3.5 wt.% NaCl solution. The films electrodeposited with a current density of 44.4 A/dm2 shows a low self-corrosion current density of 4.72 106 A,cm2 in 3.5 wt.% NaCl solution. The corrosion mechanism was proposed in combination with electrochemical impedance spectroscopy results. The outstanding properties were attributed to the near-equimolar ternary components. The results lay a solid foundation for developing of highly oriented medium-entropy alloy films with strong corrosion resistance. |
Keywords: | Medium-entropy alloy; Compositionally complex alloy; CoNiFe film; Corrosion resistance; Electrodeposition |
Rights: | © 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
DOI: | 10.1016/j.jmrt.2022.07.175 |
Published version: | http://dx.doi.org/10.1016/j.jmrt.2022.07.175 |
Appears in Collections: | Mechanical Engineering publications |
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hdl_136703.pdf | Published version | 2.8 MB | Adobe PDF | View/Open |
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